Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9589499 | Journal of Molecular Spectroscopy | 2005 | 10 Pages |
Abstract
Approximately 150 pure rotational transitions each have been recorded for SO2, v2 = 0 and 1, in selected frequency regions up to 2 THz. The J and Ka quantum numbers reach very high values: 92 and 23, respectively, for the ground vibrational state and 81 and 21, respectively, for the first excited bending state. The highest levels accessed are almost 3000 cmâ1 above ground. The relative experimental uncertainties Îν/ν are about 10â8 for several medium to strong, isolated lines, and generally better than 2.5 Ã 10â7. Improved spectroscopic parameters have been obtained for both states, particularly for the excited bending state. In fact, the accuracies with which the energy levels of the v2 = 1 state are known depend essentially only on the accuracy with which the vibrational spacing is known from infrared spectroscopy.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Holger S.P. Müller, Sandra Brünken,