Article ID Journal Published Year Pages File Type
9589505 Journal of Molecular Spectroscopy 2005 12 Pages PDF
Abstract
High-resolution Fourier transform spectrum of the HD32S molecule was studied in the region of 5000-9000 cm−1. More than 1600 observed transitions yielded 239, 264, 131, and 116 upper state ro-vibrational energies of the states (002), (012), (003), and (013), respectively. With a Watson-type effective Hamiltonian model, the ro-vibrational parameters of these four upper states were determined by a least-square fitting which can reproduce the ro-vibrational energies close to the experimental accuracy. The relative linestrengths are also discussed.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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