| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9589586 | Journal of Molecular Spectroscopy | 2005 | 5 Pages |
Abstract
The line shape profiles of the AË2Aâ²âXË2Aâ³ 000-000 band of hydroperoxy radical (HO2) have been measured in the presence of nitrogen and water using laser photolysis/cw near infrared two-tone frequency modulation spectroscopy. On the basis of the theory described by Avetisov and Kauranen [Appl. Opt. 35 (1996) 4705], the absorption line shapes were well represented by the Voigt profile. The nitrogen- and water-broadening coefficients for the 7020.766 cmâ1 161, 16 â 160, 16F1 line of HO2 were estimated to be 0.101 ± 0.013 and 0.216 ± 0.133 cmâ1 atmâ1, respectively. The large value of water-broadening coefficient suggests the long range interaction between HO2 with water.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Nozomu Kanno, Kenichi Tonokura, Atsumu Tezaki, Mitsuo Koshi,