| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9590804 | Journal of Molecular Structure: THEOCHEM | 2005 | 6 Pages |
Abstract
Periodic motions due to nonlinear resonances of D-C and C-N stretches of DCN molecule are shown by an algorithm based on coset representatives. These motions are highly localized on either D-C or C-N bond, or that their action ratios on D-C and C-N are 2:3 or 1:1. These periodic motions bear peculiar characters not possessed by the normal modes based on the harmonic approximation. It is shown that chaotic motion is mainly due to the D-C stretch. However, quasiperiodic modes of highly localized D-C stretch are also identified.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Peijie Wang, Guozhen Wu,