Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9594578 | Surface Science | 2005 | 6 Pages |
Abstract
A combined theoretical and experimental approach is used to study water on the TiO2(0Â 1Â 1)-(2Â ÃÂ 1) surface. Based on simple proximity arguments dissociative adsorption is expected. Density functional theory and photoemission spectroscopy show that, at low temperatures, a mixed molecular/dissociated water monolayer is stabilized by a H-bonding network. Scanning tunneling microscopy and molecular dynamics simulations provide evidence of a dissociated layer with a preferential non-uniform arrangement of the adsorbates at room temperature.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
T.J. Beck, Andreas Klust, Matthias Batzill, Ulrike Diebold, Cristiana Di Valentin, Antonio Tilocca, Annabella Selloni,