| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9594790 | Surface Science | 2005 | 10 Pages |
Abstract
Experimental studies indicate that the N2O-CO reaction occurring on Pd(1Â 1Â 0) under UHV conditions exhibits a first-order kinetic phase transition in the steady-state case and also transient kinetics strongly dependent on the initial state of the system. We construct a mean-field kinetic model describing these phenomena. With a minimal number of the fitting parameters, the model reasonably reproduces the special features of the reaction kinetics.
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Physical and Theoretical Chemistry
Authors
Vladimir P. Zhdanov, Yunsheng Ma, Tatsuo Matsushima,