| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9595601 | Surface Science | 2005 | 10 Pages |
Abstract
The adsorption and dissociation of cyclobutanone on a β-Mo2C foil was studied using RAIRS, XPS and TPD. Adsorption at 105 K populates η1 and η2 states in a 5:1 ratio. Heating to 170-300 K causes scission of the carbonyl bond and the development of RAIRS spectra characteristic of a cyclobutylidene-oxo surface complex. This dissociation chemistry is compared to literature data for the interaction of ketones with a single-metal atom tungsten complex.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
M. Siaj, H. Oudghiri Hassani, E. Zahidi, P.H. McBreen,