Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9609769 | Applied Catalysis B: Environmental | 2005 | 6 Pages |
Abstract
Photocatalytic degradation of trichloroethylene (TCE) was investigated using a tubular photoreactor packed with TiO2 powders prepared by sol-gel techniques. Powders of the following metals: Cr, Fe, Ni, Cu and Pt, or Ca(OH)2 were uniformly mixed with the TiO2 powders and then their effect on the formation of COCl2, CHCl3, and CHCl2COCl as by-products was examined. Concentrations of COCl2 and CHCl3 were determined in a product gas stream by GC/MS while CHCl2COCl accumulated on the catalyst surface. When the catalysts were immersed in water after TCE photodegradation, the formation of Cl- and CHCl2COOâ ions was confirmed by ion-chromatography. Of the chemicals tested, only Cu and Ca(OH)2 inhibited the formation of the chlorinated by-products. With increasing Cu and Ca(OH)2 content, TCE conversion decreased while the stoichiometric ratio ([CO2]formed/[TCE]degraded) increased. Concentrations of COCl2, CHCl3, and CHCl2COCl decreased with increasing Cu and Ca(OH)2 content. Especially, the formation of COCl2 was remarkably suppressed with Ca(OH)2.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Toshifumi Tanimura, Atsushi Yoshida, Suzuko Yamazaki,