In situ MRI of the structure and function of multiphase catalytic reactors

NMR imaging (MRI) was used to study the distribution of the liquid phase in an operating trickle bed reactor using hydrogenation of α-methylstyrene or n-octene-1 as representative examples. In a single pellet reactor, the existence of oscillating regimes under unchanged external conditions was shown. The experiments with packed beds have demonstrated the non-uniform distribution of the liquid phase over the bed, the presence of partially liquid-filled or completely dry catalyst particles in the operating reactor, and the existence of liquid phase transport between liquid-filled and dry catalyst particles. Detection of spatially resolved NMR spectra was used to characterize chemical conversion variations within the operating reactor. Preliminary MRI results for an operating monolithic reactor were obtained. It was found that MRI can be used to directly image solid materials using NMR signal detection of nuclei other than 1H. In particular, imaging of alumina using 27Al NMR signal appears highly promising for the development of novel MRI applications in chemical engineering and catalysis, including spatially resolved NMR thermometry.