| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614395 | Journal of Molecular Catalysis A: Chemical | 2005 | 10 Pages |
Abstract
Experimental conditions for palladium-catalysed hydrogenolysis of tetrazolyl and benzisothiazolyl naphthylmethylic ethers, with a hydrogen donor and with molecular hydrogen, were investigated. Analysis of the structure and reactivity indicates that these compounds are structurally similar to the corresponding benzyloxyderivatives around the ether bond but exhibit different reactivity. It can be concluded from this investigation that 5-chloro-1-phenyltetrazole acts as a better derivatizing agent for naphthyl methanols than 3-chloro-1,2-benzisothiazole-11-dioxide, this contrasting with what has been observed with phenols, allylic and benzylic alcohols.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
LuÃs M.T. Frija, M. Lurdes S. Cristiano, Emanuel M.O. Guimarães, Nelson C. Martins, Rui. M.S. Loureiro, Jamie F. Bickley,