Article ID Journal Published Year Pages File Type
9614401 Journal of Molecular Catalysis A: Chemical 2005 7 Pages PDF
Abstract
Active solid oxidation catalysts can be obtained by incorporating dioxomolybdenum(VI) species derived from MoO2Cl2(OPMePh2)2 into silica matrices via a sol-gel method, and can catalyze epoxidation. The supported catalyst has been characterized by elemental analysis, XRD, N2-physisorption, FT-IR, FT-Raman, UV-vis and solid-state MAS NMR spectroscopies, and a pathway for the reaction between MoO2Cl2(OPMePh2)2 and tetraethoxysilane (TEOS) is suggested.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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