Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9614401 | Journal of Molecular Catalysis A: Chemical | 2005 | 7 Pages |
Abstract
Active solid oxidation catalysts can be obtained by incorporating dioxomolybdenum(VI) species derived from MoO2Cl2(OPMePh2)2 into silica matrices via a sol-gel method, and can catalyze epoxidation. The supported catalyst has been characterized by elemental analysis, XRD, N2-physisorption, FT-IR, FT-Raman, UV-vis and solid-state MAS NMR spectroscopies, and a pathway for the reaction between MoO2Cl2(OPMePh2)2 and tetraethoxysilane (TEOS) is suggested.
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Authors
Ge Wang, Linsheng Feng, Rudy L. Luck, David G. Evans, Zhiqiang Wang, Xue Duan,