| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614411 | Journal of Molecular Catalysis A: Chemical | 2005 | 5 Pages |
Abstract
Novel rhodium-1,3-dialkylperhydrobenzimidazolin-2-ylidene (2a,b) and 1,3-dialkylimidazolin-2-ylidene complexes (4a,b) have been prepared and characterized by C, H, N analysis, 1H NMR and 13C NMR. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amount of the new rhodium(I)-carbene complexes, RhCl(COD)(1,3-dialkylperhydrobenzimidazolin-2-ylidene) or RhCl(COD)(1,3-dialkylimidazolin-2-ylidene) to give the corresponding silylethers in good yields (63-99%).
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Murat YiÄit, Ismail Ãzdemir, Bekir Ãetinkaya, Engin Ãetinkaya,