Article ID Journal Published Year Pages File Type
9614441 Journal of Molecular Catalysis A: Chemical 2005 7 Pages PDF
Abstract
Various types of the surface zirconocene species [(C) and (D) in the scheme below and [Me2Si(Ind)2ZrCl]+[MeMAO]− (E)] are identified in the supported catalysts Me2Si(Ind)2ZrX2/MAO/SiO2 (X = Cl, Me) by means of UV/vis in diffusion reflection mode (DRS) and DRIFT spectroscopy. It is shown the species of (D) type are formed only at the interaction of the supported catalysts with TIBA.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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