Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9614488 | Journal of Molecular Catalysis A: Chemical | 2005 | 7 Pages |
Abstract
Bis(maltolato)oxovanadium complexes have been covalently bonded to carbamated modified silica gel and shown to act as catalysts for the oxidation of cyclohexane by dioxygen, to cyclohexanol and cyclohexanone with a good activity and selectivity, without any additive and under relatively mild reactions. The effects of various factors were investigated towards the optimization of the reaction conditions and evidence is presented for a free-radical mechanism.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Gopal S. Mishra, Armando J.L. Pombeiro,