Article ID Journal Published Year Pages File Type
9614527 Journal of Molecular Catalysis A: Chemical 2005 8 Pages PDF
Abstract
A Pd-C shell at ca. 3.6 Å can be included in the EXAFS fitting to the Pd/C catalyst prepared by PdCl2 or Pd(NO3)2 impregnation. The model of precursor anchoring by surface oxygen groups is not supported by EXAFS. This Pd-C interaction was originally proposed [1] for Pd(NH3)4Cl2/C. It indicates the presence of a similar Pd-C interaction in the Pd/C catalysts from cationic, anionic, and neutral Pd precursors.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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