Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9614561 | Journal of Molecular Catalysis A: Chemical | 2005 | 6 Pages |
Abstract
Several novel sulfonyl chloride functionalized ionic materials were used as media and catalysts for Beckmann rearrangement of cyclohexanone oxime and satisfactory results were achieved under mild conditions. The effects of all parameters were discussed. Moreover the deactivation of ionic liquid catalytic system during the recycle was investigated by using FTIR spectroscopy and mass balance calculation. The trapping of acidic ionic material with basic product is proved to be mainly responsible for the difficulties encountered in the reuse of this type of material. A possible mechanism was conjectured.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Zhengyin Du, Zuopeng Li, Yanlong Gu, Juan Zhang, Youquan Deng,