| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614574 | Journal of Molecular Catalysis A: Chemical | 2005 | 7 Pages |
Abstract
A quantitative approach is successfully used in the ESR study of catalysts for olefin metathesis [Wn+(Mon+)-ionic liquid-olefin]. The key role of isolated complexes of W5+ and Mo5+ ions in catalysis is demonstrated. The kinetics of formation/accumulation of the isolated W5+ species at the initial step of W6+ reduction by an olefin agrees closely with the kinetics of metathesis.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
![Catalytically active species in new metathesis systems [Wn+(Mon+)-ionic liquid-olefin]: A quantitative ESR study](/preview/png/9614574.png "First Page Preview: Catalytically active species in new metathesis systems [Wn+(Mon+)-ionic liquid-olefin]: A quantitative ESR study")
Authors
A.V. Kucherov, A.V. Vasnev, A.A. Greish, L.M. Kustov,