| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614602 | Journal of Molecular Catalysis A: Chemical | 2005 | 7 Pages |
Abstract
An interference-free tandem catalysis, based on [(2-ArNC(CH3))2C5H3N]FeCl2 (Ar = 2-Cl-4-CH3C6H3)/MAO and /TiCl4/MgCl2/MAO, was used for the synthesis of branched polyethylene with ethylene as the only monomer stock. The deactivation due to the side reactions of catalysts and cocatalysts could be totally avoided because MAO was used as the sole cocatalyst. By changing the reaction conditions and Fe/Ti molar ratio, a series of branched polyethylene with different branching degrees were effectively produced.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Zhicheng Zhang, Zhanxia Lu, Shangtao Chen, Huayi Li, Xiaofan Zhang, Yingying Lu, Youliang Hu,