Article ID Journal Published Year Pages File Type
9614612 Journal of Molecular Catalysis A: Chemical 2005 7 Pages PDF
Abstract
The use of 2,2′-bioxazolyl ligands with bulky substituents at the 4,4′-position effectively accelerated the Pd-catalyzed oxidative carbonylation of phenol to produce diphenyl carbonate (DPC); the TONs of DPC were methyl < benzyl < iso-butyl < tert-butyl. The addition of molecular sieve 3A prevented CO2 formation, partly due to suppression of the reaction between CO and water.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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