| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614654 | Journal of Molecular Catalysis A: Chemical | 2005 | 7 Pages |
Abstract
The selective dimerization of styrene to 1,3-diphenyl-1-butene over Pd(β-diketonate)2/BF3OEt2 catalyst systems in both “phosphine-free” and “phosphine-modified” fashions has been investigated. Styrene dimers up to 95% consists of trans-1,3-diphenyl-1-butene. Reaction products were characterized with 1H, 13C NMR, IR, MS-GC spectroscopy and GC analysis. Palladium hydride complexes are likely to be catalytically active species.
Related Topics
Physical Sciences and Engineering
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Catalysis
Authors
Gomboo Myagmarsuren, Vitalii S. Tkach, Fedor K. Shmidt, Mesyef Mohamad, Dmitrii S. Suslov,