Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9614685 | Journal of Molecular Catalysis A: Chemical | 2005 | 9 Pages |
Abstract
The screening of metal nitrates revealed the ability of Bi(NO3)3·5H2O and Fe(NO3)3·9H2O as catalyst for the Ferrier O-glucosylation using 3,4,6-tri-O-acetyl-d-glucal. The Bi(NO3)3·5H2O-mediated O-glucosylation show substantial solvent dependency and enhanced reaction rate in [bmim][PF6] than in the conventional organic solvents. Apart from the ambient quality, eco-friendly nature and catalyst economy, the Bi(NO3)3·5H2O/[bmim][PF6] method offers good yields and high anomeric selectivity, reduced catalyst concentration, reduced reaction time and recyclability of reaction medium.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Prashant U. Naik, Susheel J. Nara, Jitendra R. Harjani, Manikrao M. Salunkhe,