Article ID Journal Published Year Pages File Type
9614685 Journal of Molecular Catalysis A: Chemical 2005 9 Pages PDF
Abstract
The screening of metal nitrates revealed the ability of Bi(NO3)3·5H2O and Fe(NO3)3·9H2O as catalyst for the Ferrier O-glucosylation using 3,4,6-tri-O-acetyl-d-glucal. The Bi(NO3)3·5H2O-mediated O-glucosylation show substantial solvent dependency and enhanced reaction rate in [bmim][PF6] than in the conventional organic solvents. Apart from the ambient quality, eco-friendly nature and catalyst economy, the Bi(NO3)3·5H2O/[bmim][PF6] method offers good yields and high anomeric selectivity, reduced catalyst concentration, reduced reaction time and recyclability of reaction medium.
Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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