| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614745 | Journal of Molecular Catalysis A: Chemical | 2005 | 6 Pages |
Abstract
IrCl3, a sluggish catalyst in alkaline media, surpasses catalytic efficiency of osmium and ruthenium in aqueous perchloric acid medium in the oxidation of aliphatic ketones by ceric perchlorate. Following rate law explains all findingsâd[Ce(IV)]dt=2kK1K2[CeIV][S][IrIII][H+]1+K1K2[CeIV][S]
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Praveen K. Tandon, Sumita Sahgal, Alok K. Singh, Gayatri Gayatri, Manisha Purwar,