| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614753 | Journal of Molecular Catalysis A: Chemical | 2005 | 8 Pages |
Abstract
Some Mn(III) porphyrin complexes were evaluated as catalysts in the oxidation of indane and tetralin with H2O2 in the presence of ammonium acetate. Catalysis by Mn(III)TDCPPCl gave rise mainly to monooxygenation products, but in over-oxidation conditions, hydroxy-keto compounds were selectively obtained. Catalysis by Mn(III)TF5PPCl leaded to dehydrogenated products and several studies to understand the reaction pathways were undertaken.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Susana L.H. Rebelo, Mário M.Q. Simões, M. Graça P.M.S. Neves, Artur M.S. Silva, Pietro Tagliatesta, José A.S. Cavaleiro,