| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614755 | Journal of Molecular Catalysis A: Chemical | 2005 | 9 Pages |
Abstract
Square-planar cobalt diimine pyridine complexes LCoR are active in the hydrogenation of monosubstituted and disubstituted olefins; sterically more hindered trisubstituted olefins do not react. Intermediate alkyl species of the hydrogenation cycle were detected. The mechanism was further investigated by EPR measurements and DFT calculations.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Quinten Knijnenburg, Andrew D. Horton, Harry van der Heijden, T. Martijn Kooistra, Dennis G.H. Hetterscheid, Jan M.M. Smits, Bas de Bruin, Peter H.M. Budzelaar, Anton W. Gal,