| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614759 | Journal of Molecular Catalysis A: Chemical | 2005 | 8 Pages |
Abstract
The exchange of the Rh/Triphenylphosphine trisulfonate sodium [TPPTS] complex on to an anion exchange resin results in a stable heterogenized catalyst for the hydroformylation of alkenes. The kinetics of hydroformylation of 1-hexene using Rh/TPPTS complex exchanged on anion exchange resin to Amberlite IRA-93 has been investigated for the first time. The rate of the reaction was found to be dependent on the partial pressure of hydrogen and 1-hexene concentrations with a first order. A maximum in the rate with increasing partial pressure of carbon monoxide was observed. A rate model has been proposed which predicts the observed rate data within reasonable error. The activation energy was found to be 84.37Â kJ/mol.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
M.M. Diwakar, R.M. Deshpande, R.V. Chaudhari,