| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9614768 | Journal of Molecular Catalysis A: Chemical | 2005 | 8 Pages |
Abstract
β-Diketiminato Ni(II) complexes/MAO system catalyzed the isomerization and oligomerization of 1-hexene were investigated. The obtained products involve trans- and cis-2-hexenes and various dimer isomers. The “walking” of the Ni(II) atom from a secondary carbon to another one along the alkyl chain of the m-Ni-alkyl intermediates is blocked in the β-diketiminato Ni(II)/MAO catalyst system.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Junkai Zhang, Haiyang Gao, Zhuofeng Ke, Feng Bao, Fangming Zhu, Qing Wu,