Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9614875 | Journal of Molecular Catalysis A: Chemical | 2005 | 7 Pages |
Abstract
Ag and Cu-catalysed heterogeneous epoxidation of alkenes is a strong function of the identity of the metal, the presence or otherwise of allylic H atoms, and the stereochemistry of the alkene. Halogens and nitrate promote selectivity by an electronic effect and direct oxygen transfer, respectively.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Richard M. Lambert, Federico J. Williams, Rachael L. Cropley, Alejandra Palermo,