Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9618652 | Solar Energy Materials and Solar Cells | 2005 | 15 Pages |
Abstract
We report the electrical and optical properties of molecular films made of homogeneous and segregated mixtures of polythiophene with both C60 and C60(OH)24-28 compounds, and relate the trends observed with theoretical predictions based on systematic studies of the electronic structure and energetics of polyhydroxylated fullerenes. The electric and optical properties are strongly correlated to the degree of phase segregation in the molecular films and also to the tendency of the hydroxyl groups to cluster on the C60 cage, thus providing useful information on the potential of hydroxylated fullerenes for the development of buffer layers for fullerene/conductive polymer solar cells. Finally, we underline the importance of quantifying the changes in the electronic structure of the C60 molecules when the chemical functionalization of their surfaces is performed in order to better understand and improve the efficiency of fullerene-based solar cell materials.
Related Topics
Physical Sciences and Engineering
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Authors
M.E. Rincón, R.A. Guirado-López, J.G. RodrÃguez-Zavala, M.C. Arenas-Arrocena,