Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9625611 | Electrochimica Acta | 2005 | 7 Pages |
Abstract
Charge transfer processes in poly-3-methylthiophene (PMT) and poly-3-octylthiophene (POT) film electrodes bathed with 0.05-0.5Â M LiClO4 acetonitrile solutions were studied by cyclic voltammetry and electrochemical impedance spectroscopy. Semi-circle parameters Rct and Cdl, Warburg constant Ïw, effective diffusion coefficients Deff, and low-frequency capacities CLF were determined for PMT and POT films as functions of the bathing electrolyte concentration and the electrode potential. A comparison between the results of electrochemical studies of PMT and POT modified electrodes is performed in the paper.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
E.G. Tolstopyatova, S.N. Sazonova, V.V. Malev, V.V. Kondratiev,