Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9626077 | Fluid Phase Equilibria | 2005 | 10 Pages |
Abstract
Diffusion in liquids can still be predicted only with high uncertainty due to the lack of sufficient experimental data. Diffusion experiments are complex and time-consuming. Furthermore, the concentration dependence of the diffusion coefficients requires usually several experiments even for binary mixtures. The possibility to extract this information from one short Raman diffusion experiment is explored here. A general identification framework is provided which does not require the a priori specification of a diffusion coefficient model structure but establishes the concentration dependence directly from the data. The methodology is used to determine the diffusion coefficient in the mixture ethyl acetate-cyclohexane in a wide concentration range.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
André Bardow, Volker Göke, Hans-Jürgen KoÃ, Klaus Lucas, Wolfgang Marquardt,