Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9634204 | Journal of Electroanalytical Chemistry | 2005 | 7 Pages |
Abstract
The electrochemical behaviour of Ir(1Â 1Â 1) electrodes has been studied in simple aqueous solutions, in the presence and absence of various adsorbates: sulphate, phosphate and halide anions. In general, this electrode is very similar to Pt(1Â 1Â 1); however, the rates and relative strengths of adsorption are different. In the accessible potential range no capacitance peak similar to that of Pt(1Â 1Â 1) was found, and no Gouy-Chapman minimum could be identified. CO adlayer stripping from Ir(1Â 1Â 1) in sulphuric acid occurs in the same potential region as for Pt(1Â 1Â 1).
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Authors
T. Pajkossy, L.A. Kibler, D.M. Kolb,