Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9681069 | Desalination | 2005 | 8 Pages |
Abstract
We attempted to produce reverse osmosis membranes with 5-chloroformloxy-isophthaloyl chloride (CFIC) and m-phenylenediamine (MPD) with an interfacial polymerization technique on the polysulphone supporting film. The membranes produced were characterized using permeation experiments with salt water. Attenuated total reflectance infrared (ATR-IR), X-ray photoelectronic spectroscopy (XPS), as well as imaging using scanning electronic microscopy (SEM) were used. The results show that the active layer of a CFIC/MPD TFC membrane is polyamideurethane, including an amide functional group (-CONH-), urethane functional group (-OCONH-) and hydroxyl functional group (-OH). The flux and rejection of a CFIC/MPD TFC membrane are better than a TMC/MPD TFC membrane in the same condition (concentrations of CFIC = 0.15 wt% and contact time with the organic solution is 20 s, which is the best preparation parameter) and the surface of the CFIC/MPD TFC membrane is a dense, finely dispersed grainy structure.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Filtration and Separation
Authors
Yong Zhou, Sanchuan Yu, Meihong Liu, Congjie Gao,