Article ID Journal Published Year Pages File Type
9693957 Thermochimica Acta 2005 5 Pages PDF
Abstract
Ternary excess molar enthalpies for (1-propanol + 2-propanol + 1,4-dioxane) mixture have been measured with a flow calorimeter at T = 298.15 K and atmospheric pressure. Constant contours for the ternary experimental results were calculated by a polynomial equation. Further, the results have been compared with those calculated from a UNIQUAC formalism taking into consideration the molecular self- and cross-association of two alcohols and the solvation among the alcohols and 1,4-dioxane. The results predicted by using binary parameters obtained from the corresponding binary results alone are in good agreement with the experimental values.
Related Topics
Physical Sciences and Engineering Chemical Engineering Fluid Flow and Transfer Processes
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