| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9693978 | Thermochimica Acta | 2005 | 11 Pages |
Abstract
The temperature-modulated differential scanning calorimetry (TMDSC) responses during cure of both epoxy/aromatic amine and dicyanate ester/polycyanurate systems are modeled using chemical reaction kinetics with diffusion control. Physical aging effects are incorporated into the model using the Tool-Narayanaswamy-Moynihan (TNM) equation. We investigate the assumption that the mobility factor, which may be obtained from experimental temperature-modulated differential scanning calorimetry reversing heat flow data, is related to the diffusion factor for the two systems.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Fluid Flow and Transfer Processes
Authors
Yan Meng, Sindee L. Simon,