| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9694088 | Thermochimica Acta | 2005 | 5 Pages |
Abstract
Ethylene molecules are considered to oligomerize in the interlayer nano-space of ternary graphite intercalation compounds (GICs), CsC24(C2H4)x; however, the mechanism and the degree of oligomerization have not yet been clarified. In the present study, the released gases from CsC24(C2H4)1.4 at high temperatures were investigated by TG/GC-MS under helium atmosphere. The detection of alkanes (C3-C20) by TG/GC-MS analysis in both the trap and direct modes supported the existence of the oligomers in the nano-space. Other gases such as water vapor, methane, etc., were also detected.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Fluid Flow and Transfer Processes
Authors
R. Matsumoto, T. Arii, Y. Oishi, Y. Takahashi,