| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9694099 | Thermochimica Acta | 2005 | 4 Pages |
Abstract
Although plant experience is essential, it is possible to assess the hazard of large scale process operation using a logical process based on experimental data. This paper reported an analytical procedure to characterize the reaction and the decomposition kinetics for organic peroxide near its self-accelerating decomposition temperature (SADT) by means of isothermal calorimetric data in a thermal activity monitor (TAM). As a result, a complex reaction where autocatalysis or some physical phenomena may take place was determined. And consequently the SADT in full-scale packages for such an autocatalytical substance was estimated.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Fluid Flow and Transfer Processes
Authors
Xin-Rui Li, Hiroshi Koseki,