Co-aggregation of fullerene C60 and thiophene in the non-aromatic solvent cyclohexene

Co-aggregation of fullerene C60 and thiophene has been studied calorimetrically in cyclohexene at 25 °C. The total aggregation heat is found to depend on initial concentration of thiophene and fall between −1.9 and −5.8 kJ mol−1. The corresponding thiophene/fullerene molar ratio (“co-aggregation number”) ranges from 7 to 12. The data are rationalized by formation of heteromolecular nanoaggregates with intermolecular contacts of both fullerene-thiophene and fullerene-fullerene types. A physical model describing interaction between fullerenes and π-donors in solution is substantiated and used to explain heterogeneity of composites containing fullerenes.