Article ID Journal Published Year Pages File Type
974331 Physica A: Statistical Mechanics and its Applications 2016 19 Pages PDF
Abstract

•The generalized Langevin equation is solved analytically for a viscoelastic fluid.•Alternative stochastic equations are derived for a diffusing dense fluid particle.•The Fluctuation–Dissipation theorem is generalized for a fluid in an external field.•A self-contained definition of diffusion coefficient is provided.•The short time dynamics within absorbing boundaries fits the MD simulations.

The non-static generalized Langevin equation and its corresponding Fokker–Planck equation for the position of a viscous fluid particle were solved in closed form for a time dependent external force. Its solution for a constant external force was obtained analytically. The non-Markovian stochastic differential equation, associated to the dynamics of the position under a colored noise, was then applied to the description of the dynamics and persistence time of particles constrained within absorbing barriers. Comparisons with molecular dynamics were very satisfactory.

Related Topics
Physical Sciences and Engineering Mathematics Mathematical Physics
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