Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9746530 | Food Chemistry | 2005 | 7 Pages |
Abstract
A condensation reaction between malvidin 3-glucoside (mv3gl) and catechin (cat) mediated by acetaldehyde and propionaldehyde was conducted in model solutions at two pH values (at 1.5 and 3.2). Acetaldehyde led to the formation of mv3gl-8-ethyl-8-cat (m/z at 809) widely reported in the literature, whereas propionaldehyde led to the formation of mv3gl-8-propyl-8-cat (m/z at 823) and its structural characterization is elucidated herein for the first time by 1D and 2D NMR. The formation of these alkyl-linked pigments is favoured at lower pH value as the alkyl linkage requires the formation of an aldehyde carbocation for a further condensation.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
João Pissarra, Sandra Lourenço, Ana M. González-Paramás, Nuno Mateus, C. Santos Buelga, Artur M.S. Silva, Victor De Freitas,