| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9749110 | Journal of Chromatography A | 2005 | 6 Pages |
Abstract
Dialkyl l-glutamide-derived lipids have been found to form supramolecular assemblies and to show specific properties based on their highly ordered structures in aqueous and organic media. To use these unique properties to create molecular recognition systems, dioctadecyl l-glutamide-derived lipid-grafted porous silica particles (Sil-DSG) were newly prepared and used as a stationary phase in reversed phase liquid chromatography. Compared with conventional ODS (octadecylated silica), the Sil-DSG column showed remarkably higher selectivity for polycyclic aromatic hydrocarbons (PAHs). Especially, Sil-DSG recognized the molecular linearity and planarity of PAHs. Suspension state 1H NMR and 13C CP/MAS-NMR spectroscopies showed that the alkyl chains on the Sil-DSG are in gauche form and their mobility is strongly restricted at room temperature. This paper discusses higher selectivity of Sil-DSG with a carbonyl Ï-benzene Ï interactions.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Makoto Takafuji, M. Mizanur Rahman, Hamid R. Ansarian, Mahnaz Derakhshan, Toshihiko Sakurai, Hirotaka Ihara,