| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 975482 | Physica A: Statistical Mechanics and its Applications | 2007 | 9 Pages |
Abstract
On the basis of the previously obtained non-Markovian kinetic equation for irreversible chemical reaction A+BâC+B, we have examined a model of contact reaction between hard (impenetrable) spheres (singular force potential). The nature of the additional contribution to the rate constant is explained. As is found, for reactants with a hard core it is necessary to allow for the presence of initial correlations between them. A class of initial conditions for arbitrary form of the pair potential energy is established.
Related Topics
Physical Sciences and Engineering
Mathematics
Mathematical Physics
Authors
A.B. Doktorov, A.A. Kadetov, A.A. Kipriyanov,