Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9756954 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2005 | 8 Pages |
Abstract
Electronic spectral properties also show that the sulphur donor atom of L1 weakens the ligand field with respect to ligand-to-metal charge-transfer band. However it is expected that second-row transition metal-ligand bonds tend to be weaker than third-row transition metal-ligand bonds. There are well-established examples of reactions in which decreased of reactivity down a triad of transition metals is not observed. These novelties are usually attributed to Ï-bonding effects for ligands such as carbon monoxide, solvent effects, or a change in mechanism.
Related Topics
Physical Sciences and Engineering
Chemistry
Analytical Chemistry
Authors
Sulekh Chandra, Rajiv Kumar,