Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9756993 | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy | 2005 | 5 Pages |
Abstract
The experimental Raman vibrational spectrum of the 5.94âm water solution of the beryllium(II) chloride has been acquired. Theoretical frequencies, infrared and Raman intensities of the vibrational spectrum of the beryllium cation tetrahydrate have been calculated by means of quantum chemical approach. The peaks of the experimental spectrum have been assigned on the basis of the results of the quantum-chemical calculations. It has been shown that the hydrating surrounding of the aquacation increases effectively the frequency of the beryllium-oxygen stretching vibration by 16% in comparison with the free complex.
Related Topics
Physical Sciences and Engineering
Chemistry
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Authors
Dmitry A. Rozmanov, Olga V. Sizova, Mikhail Yu. Skripkin, Kim A. Burkov,