Article ID Journal Published Year Pages File Type
975725 Physica A: Statistical Mechanics and its Applications 2007 18 Pages PDF
Abstract

In previous publications by the author the crystalline state was studied with the help of statistical methods based upon utilization of distribution functions. The approximation used for a crystal was not, however, fully adequate for fluids, which did not permit one, in particular, to construct a phase diagram with a triple and critical point. The present paper begins with analysis of the pair correlation function in crystals in order to find an approximation adequate for a crystal as well as fluid. The relevant thermodynamics is developed. It is shown that the fluid can be described, for example, by the hypernetted-chain equation or by the van der Waals or Dieterici equations of state, and such a description will be compatible with the proposed description of the crystal. A phase diagram is constructed which exhibits the region of the crystalline state together with the triple and critical points.

Related Topics
Physical Sciences and Engineering Mathematics Mathematical Physics
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