Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9765815 | Journal of Fluorine Chemistry | 2005 | 9 Pages |
Abstract
Alkyl fluoroformates RHOC(O)F are a new family of excellent alkylating agents. Perfluoroacyl fluorides, selected perfluoroketones and fluoroolefins can be alkylated to hydrofluoroethers RF-O-RH and hydrofluoroalkanes RF-RH, respectively. Potassium fluoride and cesium fluorides catalysts in glymes at 50-100 °C are the preferred experimental conditions.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Marco Galimberti, Giovanni Fontana, Giuseppe Resnati, Walter Navarrini,