| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 9765836 | Journal of Fluorine Chemistry | 2005 | 7 Pages |
Abstract
Tetrakis(dimethylamino)ethylene (TDAE) was found to be an effective electron-transfer agent that promoted the reactions of bromodifluoromethyl phenyl sulfone with aldehydes to give structurally diverse (benzenesulfonyl)difluoromethylated alcohols in good yield, which can be further transformed into difluoromethyl alcohols and 1,1-difluoro-1-alkenes via reductive desulfonylation and Julia olefination, respectively.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
G.K. Surya Prakash, Ying Wang, Jinbo Hu, George A. Olah,