Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9776367 | Synthetic Metals | 2005 | 4 Pages |
Abstract
Novel multistep procedures for preparing water-soluble, conducting star-shaped polyaniline/poly(styrenesulfonate) complex are presented. Star poly(styrenesulfonate) which serves as a template for generating the electroactive polymer complex was synthesized by sequential atom transfer radical polymerization (ATRP) and Makowski's sulfonating method of styrene. The characterization by GPC and 1H-NMR showed that each polymeric arm of the star polyelectrolyte exhibited a well-defined chain length and a well-controlled charge fraction. The conducting polymer complex prepared by the polyelectrolyte-guided polymerization of aniline was highly stable in aqueous solution.
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Authors
Chih-Chien Chu, Yih-Wen Wang, Leeyih Wang, Tong-Ing Ho,