Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9777960 | Journal of the European Ceramic Society | 2005 | 8 Pages |
Abstract
A microporous amorphous silica membrane has been synthesized by thermal conversion in air of polysilazane on a silicon nitride (Si3N4) porous substrate. The porous substrate near the surface layer was penetrated by polysilazane, and converted into mesoporous amorphous silica/Si3N4 composite layer. Then, an active molecular sieving microporous amorphous silica thin layer was synthesized on the surface of the mesoporous composite layer. The polysilazane-derived amorphous silica membrane exhibited H2 permeance of 1.3 à 10â8 mol/m2 s Pa at 573 K, and the permeability ratio of H2/N2 was measured to be 141. The effects of heat treatment condition on the meso/microporous structure development of the polysilazane-derived amorphous silica within the Si3N4 porous substrate are discussed from a viewpoint of fabricating hydrogen-permselective amorphous silica membranes through polymeric precursor route.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Y. Iwamoto, K. Sato, T. Kato, T. Inada, Y. Kubo,