Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9781794 | Journal of Physics and Chemistry of Solids | 2005 | 6 Pages |
Abstract
According to the radial distribution analysis of PbCl2 melt through pulsed neutron diffraction (PND), the Cl-coordination numbers around Pb were found to be about 4, corresponding to the peak at r=2.84Â Ã
in the correlation function G(r), and to be about 2 at r=3.40Â Ã
, respectively. These two peaks were thought to form the first coordination shell. On the contrary, the Br-coordination number around Pb was estimated at about 4. Although PbCl2 and PbBr2 have the same crystal structure, the short-range structure of the melts was quite different from each other.
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Authors
Y. Iwadate, Y. Seki, K. Fukushima, M. Misawa, T. Fukunaga, K. Itoh, T. Nakazawa, Y. Okamoto, H. Matsuura, A. Kajinami, N. Ohtori, N. Umesaki,