Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
9781799 | Journal of Physics and Chemistry of Solids | 2005 | 5 Pages |
Abstract
Electrochemical behaviors of PuN and (U, Pu)N in the LiCl-KCl eutectic melts at 773 K were investigated by cyclic voltammetry. The electrochemical dissolution of PuN and (U, Pu)N began nearly at â0.90±0.05 and â0.95±0.05 V (vs. Ag+/Ag), respectively. The rest potentials of PuN and (U, Pu)N were observed at about 0.15 V more negative potential than that of UN, in the present experimental condition. The observed rest potentials of (U, Pu)N depended on the equilibrium potential of the Pu3+/PuN. In the cyclic voltammogram measured by use of (U, Pu)N as the working electrode, a steep rise of the positive current was observed at potentials more positive than â0.45 V in analogy with the cyclic voltammogram measured by use of UN as the working electrode. These indicate that UN and PuN in (U, Pu)N would be dissolved independently irrespective of forming the solid solution.
Related Topics
Physical Sciences and Engineering
Materials Science
Electronic, Optical and Magnetic Materials
Authors
O. Shirai, T. Kato, T. Iwai, Y. Arai, T. Yamashita,